胡桂春,李玉民,王 庆,付时雨,吴光远,化新通.半纤维素-甲基纤维素复合膜的制备及其性能分析[J].中国造纸学报,2019,34(1):21-26 本文二维码信息
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半纤维素-甲基纤维素复合膜的制备及其性能分析
Study on the Properties of Composite Film Prepared from Hemicelluloses and Methylcellulose
  
DOI:10.11981/j.issn.1000-6842.2019.01.21
中文关键词:  半纤维素  甲基纤维素  山梨醇  复合膜
Key Words:hemicelluloses  methylcellulose  sorbitol  composite film
基金项目:山东省自然科学基金(No.ZR2017PC020和ZR2017LF027);华南理工大学制浆造纸国家重点实验室开放基金(No.201606);制浆造纸科学与技术教育部重点实验室(No.KF2015019和KF201603)。
作者单位
胡桂春1,2,3 1.齐鲁工业大学轻工科学与技术学院山东济南250353
2.华南理工大学制浆造纸工程国家重点实验室广东广州510640
3.齐鲁工业大学制浆造纸科学与技术教育部重点实验室山东济南250353 
李玉民4 4.北辰机电集团有限公司山东济南250353 
王 庆1,3 1.齐鲁工业大学轻工科学与技术学院山东济南250353
3.齐鲁工业大学制浆造纸科学与技术教育部重点实验室山东济南250353 
付时雨2 2.华南理工大学制浆造纸工程国家重点实验室广东广州510640 
吴光远1 1.齐鲁工业大学轻工科学与技术学院山东济南250353 
化新通1 1.齐鲁工业大学轻工科学与技术学院山东济南250353 
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中文摘要:
      将甲基纤维素和山梨醇分别添加到半纤维素中制备半纤维素-甲基纤维素复合膜及半纤维素-山梨醇复合膜,对复合膜的成膜性和强度性能进行分析,并探讨半纤维素-甲基纤维素及半纤维素-山梨醇混合溶液的粒径和Zeta电位。结果表明,随着甲基纤维素质量分数增加,半纤维素-甲基纤维素混合溶液粒径先增大后减小;Zeta电位则随着甲基纤维素质量分数的增加先降低后提高,甲基纤维素质量分数为75%时,半纤维素-甲基纤维素混合溶液的Zeta电位达到最小值。当甲基纤维素质量分数为35%时,可形成完整的半纤维素-甲基纤维素复合膜,增加甲基纤维素质量分数,复合膜强度提高;当甲基纤维素质量分数为75%时,复合膜强度最大,但继续增加甲基纤维素的质量分数,复合膜强度降低。山梨醇质量分数为35%~50%时,可形成完整的半纤维素-山梨醇复合膜,且随着山梨醇质量分数增加,复合膜强度降低。
Abstract:
      To improve the film-forming property of hemicellulose, the methylcellulose and sorbitol were added respectively to form composite films and the film-forming and strength property were investigated. The particle size and Zeta potential of the hemicelluloses-methylcellulose and hemicellulose-sorbitol mixed solution were also investigated. The results showed that with the increase of methylcellulose dosage, the size of hemicelluloses-methylcellulose mixed solution particles increased first then reduced and the Zeta potential reduced first then increased. When the methylcellulose dosage was 75%, the Zeta potential reached the minimum. The continuous hemicellulose-methylcellulose film was formed when the methylcellulose addition was at least 35%. The hemicellulose-sorbitol film was continuous when the sorbitol addition ranged from 35% to 50%. The strength property of hemicellulose-sorbitol composite film decreased with the increase of sorbitol content. The strength property of hemicelluloses-methylcellulose composite film improved with the increases of methylcellulose and reached a maximum value when the methylcellulose dosage was 75%, however the strength property of the composite film decreased as the methylcellulose dosage was higher than this value.
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